Anomalous Behaviour of Beryllium

IMPORTANT

Anomalous Behaviour of Beryllium: Overview

This topic covers concepts, such as, Anomalous Properties of Beryllium, Covalent Nature of Beryllium, Reactions of Beryllium and Aluminium with Halide & Use of Beryllium and Aluminium Halides in Friedel Craft's Reaction etc.

Important Questions on Anomalous Behaviour of Beryllium

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Beryllium and aluminium exhibit many properties which are similar. But, the two elements differ in:

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A metal M readily forms water soluble sulphate   MS O 4 .  Water insoluble hydroxide   M (OH) 2  and oxide MO which becomes inert on heating. The hydroxide is soluble in NaOH. Then M is

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Give reason why beryllium does not exhibit coordination numbers more than four.

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Beryllium does not exhibit coordination numbers more than _____ as in its valence shell there are only four orbitals.

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Beryllium does exhibit coordination number more than four.

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Write a short note on beryllium oxide.

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Like aluminium, beryllium is not readily attacked by acids because of the presence of an oxide film on the surface of the metal. This exhibits _____ between beryllium and aluminium.

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Both aluminium and beryllium remain passive towards acids.

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Explain how beryllium and aluminium reacts with an acid. Name the phenomenon exhibited by these two metals.

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Explain the structural features of the compound formed when aluminium reacts with chlorine.

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On reaction with chlorine, aluminium (III) chloride forms a dimer because

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Aluminium reacts with chlorine to form aluminium chloride which exists as

MEDIUM
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Comment on the similarity of chlorides of beryllium and aluminium.

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Mention the reason for the anomalous behaviour of beryllium. Give its uses.

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Mention the catalyst used in the Friedel craft's reactions.

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Complete the given reaction of aluminium with sodium hydroxide:

2Al+2NaOH+6H2O         2NaAlOH4+?

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Identify the product of the reaction between beryllium and sodium hydroxide:

Be+2NaOH+2H2O         ?+H2

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Explain the reaction of beryllium with concentrated acid.

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Beryllium is kinetically inert to water because of the formation of 

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Beryllium can exhibit a coordination number of 4 in its compounds.